| 李 翔1，谭习有2，游诚航1*.ZIF-67制备的磷掺杂碳催化剂及其氧还原性能[J].海南师范大学学报自科版,2020,33(1):14-17 |
| ZIF-67制备的磷掺杂碳催化剂及其氧还原性能 |
| Preparation and Oxygen Reduction Performance of ZIF-67 DerivedP-doped Carbon Catalyst |
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| DOI：10.12051/j.issn.1674-4942.2020.01.004 |
| 中文关键词: 碳催化剂 氧还原 金属有机框架 磷掺杂 |
| 英文关键词: carbon catalyst oxygen reduction metal-organic framework P-doped |
| 基金项目:海南省自然科学基金项目（218MS044）；国家自然科学基金项目（21606061）；大学生创新训练计划项目（cx?
cyxj2018015，cxcyxj2018013） |
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| 中文摘要: |
| 开发高效、廉价的碳基氧还原（ORR）催化剂是质子交换膜燃料电池等先进能源系统商业化应用的关键。以金属有机框架材料 ZIF-67为原料，通过热处理、磷掺杂等过程得到高性能的ORR催化剂。该催化剂对ORR具有优异的催化性能，相较于商业Pt/C催化剂，其具有更高中部电位（Half-wave potential）。与此同时，该催化剂还具有非常好的甲醇耐受性与稳定性，并对四电子催化过程具有非常高的选择性。 |
| 英文摘要: |
| Development of highly active carbon-based ORR catalyst is key to the commercialization of advanced energy systems like proton exchange membrane fuel cells. In this work, a P-doped carbon catalyst was fabricated by using ZIF-67 as the precursor and the catalyst exhibited high ORR performance. Compared with commercial Pt/C catalyst, the catalyst showed more positive half-wave potentials. Moreover, the catalyst also demonstrated excellent methanol tolerance and sta⁃bility, as well as a rather high selectivity towards four-electron path during the ORR procedure. |
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