| 马 杭1，2，涂必禛1，2，李利娜1，2，刘梦超1，2，华英杰1，2.PW11O39Mn（II）（H2O）5-
/D301R异相体系的可见光催
化性能研究[J].海南师范大学学报自科版,2019,32(4):362-367 |
| PW11O39Mn（II）（H2O）5-
/D301R异相体系的可见光催
化性能研究 |
| Study on Visible Light Photocatalytic Property ofPW11O39Mn(II)(H2O)5-/D301R Heterogeneous System |
| |
| DOI：10.12051/j.issn.1674-4942.2019.04.002 |
| 中文关键词: PW11O39Mn（II）（H2O）5-
/D301R 可见光催化 亚甲基蓝降解 共存离子 |
| 英文关键词: PW11O39Mn(II)(H2O)5-
/D301R visible photocatalyst methylene blue degradation co-existing ions |
| 基金项目:海南省社会发展专项（ZDYF2017083）；海南师范大学2018年度研究生创新科研课题（Hsyx-2018-24） |
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| 中文摘要: |
| 为了解决均相keggin型锰取代杂多阴离子PW11O39Mn（II）（H2O）5-［ PW11Mn］光催化剂在
水溶液中难以回收利用的问题，选用D301R弱碱性阴离子交换树脂对其进行吸附，制备了PW11Mn/
D301R光催化材料。通过有机染料亚甲基蓝（MB）的可见光降解反应考察了PW11Mn/D301R材料
的光催化性能。实验表明，PW11Mn/D301R在可见光照射下对MB有较高的光催化降解活性。此 外，还系统考察了溶液中有其他阴离子存在时对光催化降解效果的影响，并提出了作用机制。本
研究为高效利用太阳能去除水体有机染料污染物提供了一条新颖途径。 |
| 英文摘要: |
| :Keggin type Mn(II) substituted heteropolyanion PW11O39Mn(II)(H2O)5-[PW11Mn] was adsorbed onto D301R resin
to resolve the separation of catalysts in the homogeneous system. The photodegradation of the organic dye methylene blue
(MB) was carried out to evaluate the visible light photocatalytic activity of PW11Mn/D301R. The experimental results
showed that the heterogeneous system PW11Mn/D301R had high photocatalytic activity for visible light degradation of MB.
In addition, the effects of other ions in the solution on photocatalytic degradation were systematically investigated, and the
mechanism of photocatalytic reaction was proposed. This research provided a novel way to efficiently utilize sunlight to re⁃
move organic dye contaminants from water. |
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